beautynista...
it is fine to switch from one to the other depending on day to day - chemical to physical - but your mineral foundation is can say with pretty much 100% certainty interacting with the chemical sunscreen when use it. avobenzone is the chemical that they use as a good uva filter for sunscreens and it interacts with the natural sunscreen in your mineral foundation. some of the minerals themselves are sunscreens, so that is how they can say mineral foundation has a natural sun protection, which is good - you just have to use a physical blocker underneith if you are going to use mineral foundation.
what sort of physical blocker do you use? there are a lot of companies out now making physical blockers out of micronized zinc oxide and titanium dioxide. they don't need to be reapplied because they do not degrade in the sun. as long as you aren't sweating profusely, you are fine with it. and it is cosmetically appealing - goes on more like a chemical sunscreen. if you wear your makeup over that, you are getting even more protection technically. how much...probably not a lot, but it definately isn't a bad thing, right? there are a lot of good things about physical blockers. the reason people don't use them as much is because of the "white cast" they tend to leave. skinceuticals makes good micronized zinc formulations. you want to look for the word "z-cote" - that is what they call micronized zinc. the thing about mineral makeup and chemical sunscreen interaction goes for all makeup, because titanium dioxide is literally used in almost every single makeup product. it is a natural sunscreen. you will see a lot of companies touting physical blockers as "natural" because...well, they are found in nature.
while i'm at it, i'll just say that chemical sunscreens are good too. there is controversy about them, but there is about everything. you will probably notice titanium dioxide in your chemical sunscreen, but it is probably chemically coated to not interfere with avobenzone. avobenzone has many names, so you might not see it on there, but if you google the ingredients, i'm sure one of them would come up as avobenzone. i use a european sunscreen with meroxyl and it has a form of avobenzone in it too. it has a ppd (uva rating) of 31, which is extremely high. You can't achieve PPD higher than 10-15 with physical only sunscreens. On the other hand PPD of 10 blocks 1-1/10= 90% of UVA & PPD of 30 blocks 1-1/30 = 97%. So you really are only getting 7% less UVA protection with a physical block, plus you don't have to reapply and risk not getting ANY protection at all! Chemical sunscreens have the higher PPD because they combine a sunblocks and different chemical sunscreens to achieve really good protection. But you can see, the difference isn't too big a deal. It is the cosmetic appeal of chemical sunscreens that make them more desirable. So I would try z-cote if you aren't using it already.
if wearing makeup is important to you and sun-protection is something you are putting effort into, seems to me like you might as well stick with a physical blocker. you can't go wrong that route and you can look all pretty! :luv: there are cheaper brands than skinceuticals, but that is the one i use and i like it. i use both as well. oh...and make sure you apply enough. i think you need to apply an 1/8 teaspoon to the face. that doesn't seem like a lot, but it is! that is why micronized formulations are so much more appealing. otherwise you would look like a kabuki mask or a ghost.